New triazole based N-heterocyclic carbene (NHC) complexes of iridium have been synthesized and characterized by multinuclear NMR and single-crystal x-ray diffraction. The cationic complexes show promising catalytic activity in the transfer hydrogenation reduction of C=O and C=N bonds.

New triazole based N-heterocyclic carbene complexes of iridium

ACS Spring 2022

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