Upper-division undergraduate chemistry students were introduced to the concepts of molecular magnetism, metal-organic framework (MOF) chemistry, the topics of data storage density along with Kryder’s law, as well as stabilizing effects of small-molecule confinement through a simple experimental protocol. The laboratory experiment includes the synthesis of a MOF and single-molecule magnet (SMM) to eventually immobilize the SMM into the MOF matrix to afford a SMM@MOF composite featuring potentially advanced data storage capabilities. Synthetic work is complemented by numerous advanced solid-state characterization methods including thermogravimetric analysis, differential scanning calorimetry, powder x-ray diffraction, gas sorption, and magnetic measurements. In this presentation, I will discuss example data, student experiences, and how to best adapt this experimental protocol to give students a preparative education for cutting-edge inorganic and materials chemistry research.

Introducing molecular magnetism and metal-organic framework chemistry in an undergraduate laboratory

ACS Spring 2022

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