We have investigated the breadth of photoredox catalysts (PCs) that can be utilized in metal-free ring-opening metathesis polymerization (MF-ROMP). Our system’s ability to be spatiotemporally controlled using light makes it an excellent candidate for applications like stereolithography and 3D printing. However, our current PC class has limited solubility in non-polar media, which makes polymerization at high monomer concentration and in bulk a challenge. By better understanding the PC chemical space in which we can operate, we can more carefully tailor our system to meet a multitude of needs and applications.

Photoredox catalyst scope in metal-free ring-opening metathesis polymerization

Fall 2022 abstracts, posters, and presentations will launch in mid-September.

ACS Fall 2022

The official archive and repository for all ACS Meetings & Expositions abstracts and select posters or presentations.