Nano-sized spherical poly(sodium styrenesulfonate) brushes (SPB) were prepared by using self-made photo-microreactor which equipped with quartz glass spiral tubes. The significant enhancement in particle sizes from photo-microreactor as determined by DLS confirmed the successful generation of SPB. The effects of residence time and monomer concentration on SPB thickness were investigated. This work opens up a new way for continuous production of SPB.

Nano-sized spherical poly(sodium styrenesulfonate) brushes preparation by photo-emulsion polymerization in microreactor

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