I will describe my research group’s use of synthetic iron-sulfur clusters to understand the properties and reactivity patterns of iron-sulfur proteins. Emphasis will be placed on the development of methods for controlling the coordination chemistry of iron-sulfur clusters and metalloclusters more generally. Additional topics may include the extension of such methods to preparing clusters (i) with novel compositions, (ii) that bind and weaken inert small molecules, and (iii) that participate in organometallic reactivity.

Methods for manipulating synthetic iron-sulfur clusters

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