Our group is interested in developing new methods for achieving the synthesis of new amine compounds. In this presentation, we will discuss the synthesis of new azirdine and sulfamate compounds achieved through the use of Rh-catalysis. Key reactions will include the intermolecular coupling between sulfamates and olefins to generate new carbohydrate derivatives, as well as the exploration of heterogenized catalysts for aziridination and C–H functionalization.

Rh catalysts for aziridination and C–H amination

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ACS Spring 2023

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