Recent developments have demonstrated that geometrical constraint about tricoordinate P(III) can impart useful non-nucleophilic reactivity at phosphorus. In this presentation, recent developments in the use of unsymmetrical tricoordinate phosphorus compounds as reagents and catalysts for a diverse range of synthetic transformations proceeding via the P(V) oxidation state will be described. Synthetic reactions focusing on carbon-heteroatom bond forming methods will be highlighted. Physical and mechanistic studies will be described to illustrate important design principles in organophosphorus redox reactivity

Carbon-heteroatom bond forming reactions with organophosphorus reagents and catalysts

Where thousands of chemistry professionals meet to share ideas and advance scientific and technical knowledge. Spring 2023 abstracts, posters, and presentations will launch at the end of March.

ACS Spring 2023

The official archive and repository for all ACS Meetings & Expositions abstracts and select posters or presentations.